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2019 Vol.24, Issue 3 Preview Page

Research Article

An Experimental Study of Propene Reaction of a Laminar Flow Reactor and Validation of its Reduced Mechanism

층류 유동반응기를 이용한 프로핀 반응 실험 및 축소 메커니즘의 검증

Cheon Hyeon Cho1
,
Ka Ram Han1
,
Chae Hoon Sohn1*
,
Jeongsik Han2
조 천현1
,
한 가람1
,
손 채훈1*
,
한 정식2
1Department of Mechanical Engineering, Sejong University
2Agency for Defense Development
1세종대학교 기계공학과
2국방과학연구소
* Corresponding Author
30 September 2019. pp. 9-16
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Abstract

Flow reactors are classified into laminar flow, turbulent flow and jet-stirred reactors depending on flow condition. Laminar flow reactor is a device that measures oxidation process of gaseous fuel and vaporized liquid fuels. Propene oxidation process was observed in a laminar flow reactor with a specified residence time at 6 atm, 968 K, and equivalence ratio of 0.71 and compared with numerical simulations. The Aramco 2.0 chemistry was adopted as a kinetic mechanism which includes 493 species and about 2,700 reaction steps. Oxygen, carbon monoxide, and carbon dioxide concentrations were measured. Numerical results with a time shift of 0.216 s show a good agreement with experimental results. And, a reduced kinetic mechanism was generated and validated based on the Aramco 2.0. The reaction steps are reduced by 23%.

Keywords
Propene
Laminar flow reactor
Reduced mechanism
References
1
S.M. Burke, W. Metcalfe, O. Herbinet, F. Battin-Leclerc, F.M. Hass, J. Stantner, F.L. Deryer, H.J. Curran, An experimental and modeling study of propene oxidation. Part 1 : Speciation measurements in jet-stirred and flow reactors, Combust. Flame, 161 (2014) 2765-2784.
10.1016/j.combustflame.2014.05.010
2
P. Dagust, M. Cathonnet, J.C Boettner, Experimental study and kinetic modeling of propene oxidation in a jet stirred flow reactor, J. Phys. Chem., 92 (1988) 661-671.
10.1021/j100314a019
3
S.G Davis, C.K. Law, H. Wang, Propene pyrolysis kinetics in a flow reactor and laminar flames, Combust. Flame, 119 (4) (1999) 375-399.
10.1016/S0010-2180(99)00070-X
4
C.K. Westbrook, W.J. Pitz, A comprehensive chemical kinetic reaction mechanism for oxidation and pyrolysis of propane and propene, Combust. Sci. Technol., 37 (1984) 117-152.
10.1080/00102208408923750
5
R.D. Wilk, N.P. Cernansky, W.J. Pitz, C.K. Westbrook, Propene oxidation at low and intermediate temperature : A detailed chemical kinetic study, Combust. Flame, 77 (1989) 145-170.
10.1016/0010-2180(89)90034-5
6
B. Heyberger, F. Battin-Leclerc, V. Warth, R. Fournet, G.M. Cȏme, G. Scacchi, Comprehensive mechanism for the gas-phase oxidation of propene, Combust. Flame, 126 (4) (2001) 1780-1802.
10.1016/S0010-2180(01)00288-7
7
K.J. Morganti, T.M. Foong, M.J. Brear, G. Silva, Y. Yang, F.L. Dryer, The research and motor octane number of liquefied petroleum gas (LPG), Fuel, 108 (2013) 797-811.
10.1016/j.fuel.2013.01.072
8
Y. Li, C.W. Zhou, K.P. Somers, K. Zhang, H.J. Curran, The oxidation of 2-Butene: A high pressure ignition delay, kinetic modeling study and reactivity comparison with isobutene and 1-Butene, Proc. Combust. Inst., 36 (1), 2017, 403-411.
10.1016/j.proci.2016.05.052
9
C.W. Zhou, Y. Li, E. O'Connor, K.P. Somers, S. Thion, C. Keesee, O. Mathieu, E.L. Petersen, T.A. Deverter, M.A. Oehlschlaeger, G. Kukkadapu, C.J. Sung, M. Alrefae, F. Khaled, A. Farooq, P. Dirrenberger, P.A. Glaude, F. Battin-Leclerc, J. Santner, Y. Ju, T. Held, F.M. Hass, F.L. Dryer, H.J. Curran, A comprehensive experimental and modeling study of isobutene oxidation, Combust. Flame, 167 (2016) 353-376
10.1016/j.combustflame.2016.01.021
10
U. Burke, W.K. Metcalfe, S.M. Burke, K.A. Heufer, P. Dagaut, H.J. Curran, A detailed chemical kinetic modeling, ignition delay time and jet-stirred reactor study of methanol oxidation, Combust. Flame, 165 (2016) 125-136.
10.1016/j.combustflame.2015.11.004
11
S.M. Burke, U. Burke, R.M. Donagh, O. Mathieu, I. Osorio, C. Keesee, A. Morones, E.L. Petersen, W. Wang, T.A. DeVerter, M.A. Oehlschlaeger, B. Rhodes, R.K. Hanson, D.F. Davidson, B. W. Weber, C.J. Sung, J. Santner, Y. Ju, F.M. Haas, F.L. Dryer, E.N. Volkov, E.J.K. Nilsson, A.A. Konnov, M. Alrefae, F. Khaled, A. Farooq, P. Dirrenberger, P.A. Glaude, F. Battin-Leclerc, H.J. Curran, An experimental and modeling study of propene oxidation. Part2: Ignition delay time and flame speed measurements, Combust. Flame, 162(2) (2015) 296-314.
10.1016/j.combustflame.2014.07.032
12
W.K Metcalfe, S.M. Burke, S.S. Ahmed, H.J. Curran, A hierarchical and comparative kinetic modeling study of C1-C2 hydrocarbon and oxygenated fuels, Int. J. Chem. Kinet., 45(10) (2013) 638-675.
10.1002/kin.20802
13
A. Kéromès, W.K. Metcalfe, K.A. Heufer, N. Donohoe, A.K. Das, C.J. Sung, J. Herzler, C. Naumann, P. Griebel, O. Mathieu, M.C. Krejci, E.L. Petersen, W.J. Pitz, H.J. Curran, An experimental and detailed chemical kinetic modeling study of hydrogen and syngas mixture at elevated pressures, Combust. Flame, 160(6) (2013) 995-1011.
10.1016/j.combustflame.2013.01.001
14
S.G. Lee, K.Y. Lee, The short reaction mechanism of premixed CH4-air flames under high pressure condition, The 43th KOSCO Symposium, 2011, 115-120.
15
K.Y. Lee, The short reaction mechanism for premixed n-Butanol/air flame, The 50th KOSCO Symposium, 2015, 225-227.
16
Y.J. Lee, K.Y. Hur, Chemical mechanism reaction and validation of methyl butanoate by automatic reduction procedure, J. Korean Soc. Combust., 21(3) (2016) 16-23.
10.15231/jksc.2016.21.3.016
17
H.S. Han, Y.G. Wang, C.J Kim, C.H. Sohn, Measurement of ignition delay time of methane/oxygen mixture by using a shock tube, J. Korean Soc. Combust., 22(1) (2017) 8-13.
18
W. Sun, Z. Chen, X. Gou, Y. Ju, An path flux analysis method for the reduction of detailed chemical kinetic mechanisms, Combust. Flame, 157(7) (2010) 1298-1307.
10.1016/j.combustflame.2010.03.006
19
X. Gou, W. Sun, Z. Chen, Y. Ju, A dynamic multi-timescale method for combustion modeling with detailed and reduced chemical kinetic mechanism, Combust. Flame, 157(6) (2010) 1111-1121.
10.1016/j.combustflame.2010.02.020
Information
  • Publisher :The Korean Society Combustion
  • Publisher(Ko) :한국연소학회
  • Journal Title :Journal of The Korean Society Combustion
  • Journal Title(Ko) :한국연소학회지
  • Volume : 24
  • No :3
  • Pages :9-16
  • Received Date : 2019-05-07
  • Revised Date : 2019-06-02
  • Accepted Date : 2019-06-04
  • DOI :https://doi.org/10.15231/jksc.2019.24.3.009
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